Product ID:012210 GASOLINE PREMIUM UNLEADED
MSDS Date:11/01/1985
FSC:9130
NIIN:00-148-7104
MSDS Number: BJVYZ

U.S. OIL CO., INC.

425 S. WASHINGTON ST.
COMBINED LOCKS, WI 54113

Emergency Phone: (414) 739-6100

Info Phone: (414) 739-6100

Cage: 9V710

U S OIL CO INC

KIMBERLY, WI 54136 US

Telephone: 920-735-8287

Cage: 9V710

PETROLEUM DISTILLATE

CAS: 68477-31-7

Fraction By Weight: >95%

ACGIH TLV: 100 PPM

BENZENE (SARA III)

CAS: 71-43-2

RTECS: CY1400000

Fraction By Weight: 1-5%

OSHA PEL 1PPM/5STEL;1910.1028

ACGIH TLV: 10 PPM; A2; 9192

EPA Report Quantity: 10 LBS

DOT Report Quantity: 10 LBS

Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES
Health Hazards Acute and Chronic:SKIN: IRRITATION, DEFATTING, &
DERMATITIS. EYE: IRRITATION, REDNESS, TEARING, & BLURRED VISION.
INHALATION: NASAL/RESPIRATORY IRRITATION, DIZZINESS, WEAKNESS,
FATIGUE, NAUSEA, HEADACHE, UNCONSCIOUSNES S, & ASPHYXIATION.
INGESTION: GASTROINTESTINAL IRRITATION, NAUSEA, VOMITING, &
DIARRHEA.
Explanation of Carcinogenicity:BENZENE IS SUSPECTED TO BE AN A2 HUMAN
CARCINOGNE.
Effects of Overexposure:INGESTION: ASPIRATION OF MATERIAL INTO THE
LUNGS CAN CAUSE CHEMICAL PNEUMONITIS & FATAL. SKIN: DEFATTING &
DERMATITIS. EYES: BLURRED VISION. INHALATION: NASAL/RESPIRATORY
IRRITATION, DIZZINESS, WEAKNE SS, FATIGUE, NAUSEA, HEADACHE,
UNCONSICOUSNESS, & ASPHYXIATION.

First Aid:EYES: FLUSH W/PLENTY OF WATER FOR AT LEAST 15 MINS. SKIN:
WASH W/SOAP & WATER. INHALATION: REMOVE TO FRESH AIR. GIVE CPR OR
OXYGEN IF NEEDED. INGESTION: DON'T INDUCE VOMITING. KEEP
WARM/QUIET. AVOID A SPIRATION OF MATERIAL INTO THE LUNGS DUE TO
VOMITING. OBTAIN MEDICAL ATTENTION IN ALL CASES.

Flash Point Method:TCC
Flash Point:-40F
Autoignition Temp:Autoignition Temp Text:UNKNON
Lower Limits:1.5%
Extinguishing Media:REGULAR FOAM, CO2, & DRY CHEMICAL.
Fire Fighting Procedures:WEAR SCBA W/FULL FACEPIECE OPERATED IN
PRESSURE-DEMAND OR OTHER POSITIVE PRESSURE MODE.
Unusual Fire/Explosion Hazard:HIGHLY VOLATILE. VAPORS MAY TRAVEL ALONG
THE GROUND OR BE MOVED BY VENTILATION & IGNITED OR OTHER IGNITION
SOURCES. FLAMMABLE LIQUID.

Spill Release Procedures:ABSORB ON PAPER/VERMICULITE/FLOOR ABSORBENT.
TRANSFER TO HOOD. REMOVE IGNITION SOURCES. STOP SPILL AT SOURCE.
DIKE AREA TO PREVENT SPREADING, PUMP TO SALVAGE TANK. TAKE UP ON
SAND, CLAY, EARTH, FLOOR ABSORBENT /SHOVEL IN CONTAINER. EVACUATE
AREA.

Handling and Storage Precautions:EMPTY CONTAINERS ARE HAZARDOUS THEY
RETAIN RESIDUES (VAPOR, LIQUID, OR SOLID). AVOID CONTACT W/EYES &
SKIN.
Other Precautions:DON'T TRANSFER TO UNLABELED CONTAINER. USE & STORE
W/ADEQUATE VENTILATION. DON'T USE CUTTING, WELDING TORCH ON & NEAR
DRUM BECAUSE PRODUCT RESIDUE CAN IGNITE EXPLOSIVELY.

Respiratory Protection:IF >TLV, A NIOSH/MSHA JOINTLY APPROVED AIR
SUPPLIED RESPIRATOR IS ADVISED IN ABSENCE OF PROPER ENVIRONMENTAL
CONTROL. IMPLEMENT ENGINEERING/ADMINISTRATIVE CONTROLS. OSHA
PERMITS NIOSH/MSHA RESPIRATORS UNDER SPECIFIED CONDITIONS.
Ventilation:PROVIDE SUFFICIENT LOCAL EXHAUST/MECHANICAL VENTILATION TO
KEEP Protective Gloves:RESISTANT, NEOPRENE, NITRILE RUBBER
Eye Protection:CHEMICAL SPLASH GOGGLES, SAFETY GLASSES
Other Protective Equipment:IMPERVIOUS CLOTHING & BOOTS.
Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE
REUSE.
Supplemental Safety and Health
LABORATORY TEST ANIMALS SUCH AS MALE RATS EXPOSED FOR 2 YEARS TO
VARIOUS LEVELS OF UNLEADED GASOLINE VAPORS SHOWED AN INCREASED
INCIDENCE OF DEGENERATIVE KIDNEY DISEASE/CANCER. FEMALE MICE
EXPOSED TO THE HIGHEST DOSE LEVEL SHOWED A SLIGHTLY HIGHER
INCIDENCE OF LIVER CANCER.

Boiling Pt:B.P. Text:80F
Vapor Pres:500
Vapor Density:4.0
Spec Gravity:0.740
Viscosity:NA
Evaporation Rate & Reference:SLOWER THAN ETHER
Percent Volatiles by Volume:100%

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS
Stability Condition to Avoid:PILOT LIGHTS, FLAMES, SPARKS, HEATERS,
SMOKING, ELECTRIC MOTORS, STATIC DISCHARGE, IGNITION SOURCES, HEAT,
& FLARES.
Hazardous Decomposition Products:TOXIC MATERIALS, CO2, CO, & VARIOUS
HYDROCARBONS.

Waste Disposal Methods:ALLOW VOLATILE PORTION TO EVAPORATE IN HOOD
VAPORS TO CLEAR HOOD DUCT WORK. DESTROY BY INCINERATION. LANDFILL
IN ACCORDANCE W/APPLICABLE REGULATIONS. FLAMMABLE LIQUID. PREVENT
RUN-OFF TO SEWERS/OTHER WATER COURSES.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.